Thermodynamic characteristics of complex formation in alumazene-pyridine system

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Authors	TIMOSHKIN Alexey Y. CONG Trinh PINKAS Jiří
Year of publication	2006
Type	Article in Proceedings
Conference	11th International Symposium on Inorganic Ring Systems
MU Faculty or unit	Faculty of Science
Citation
Field	Inorganic chemistry
Keywords	Alumazene; pyridine; static tensimetric method; B3LYP/6-31G*
Description	The thermodynamics of complex formation between the inorganic benzene alumazene AZ=[MeAlN(2,6-iPr2C6H3)]3 and pyridine Py=C5H5N has been investigated experimentally and theoretically. Thermodynamic characteristics of the complex dissociation in the temperature range 25-200 oC have been derived from the vapor pressure - temperature dependence measurements by the static tensimetric method with glass membrane as null-manometer.
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