Reaction in The Solid State. Isomerization of N-Acylselenoureas into N-Acylisoselenoureas
| Authors | |
|---|---|
| Year of publication | 2003 |
| Type | Article in Proceedings |
| Conference | Proceedings of ECSOC-7, The Seventh International Electronic Conference on Synthetic Organic Chemistry, http://www.mdpi.org/ecsoc-7.htm, September 1-30, 2003. Editors: Julio A. Seijas, De-Chun Ji and Shu-Kun Lin. CD-ROM edition |
| MU Faculty or unit | |
| Citation | |
| web | http://www.mdpi.org/ecsoc-7.htm |
| Field | Organic chemistry |
| Keywords | Solid state; isomerization; selenoureas; isoselenoureas |
| Description | Observation that some ethyl-2-(3-acylselenoureido)thiophen-3-carboxylates and their benzoanalogues undergo a photoisomerization to corresponding ethyl-2-(3-acylisoseleno-ureido)thiophen-3-carboxylates or appropriate benzoates into solid state is clarified on the base of X-ray structural analysis of some starting substances and quantum chemistry calculations for both types of compounds. |
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