Non-dietary personal pesticide exposure using silicone wristbands across 10 European countries

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Authors

FIGUEIREDO Daniel Martins MU Hongyu OSMAN Rima SILVA Vera GRAUMANS Martien MAURICE van Dael SOULEIMAN El Balkhi MOL Hans HUSS Anke VERMEULEN Roel HOFMAN Jakub ABRANTES Nelson CAMPOS Isabel ALCON Francisco CONTRERAS Josefa BALDI Isabelle BUREAU Mathilde ALAOUI Abdallah CHRIST Florian MANDRIOLI Daniele SGARGI Daria PASKOVIC Igor PASKOVIC Marija Polic GLAVAN Matjaz HARKES Paula LWANGA Esperanza Huerta GAI Lingtong NORGAARD Trine GEISSEN Violette SCHLUNSSEN Vivi SCHEEPERS Paul T. J.

Year of publication 2025
Type Article in Periodical
Magazine / Source Environment International
MU Faculty or unit

Faculty of Science

Citation
web https://www.sciencedirect.com/science/article/pii/S0160412025004854?via%3Dihub
Doi https://doi.org/10.1016/j.envint.2025.109734
Keywords Plant protection product; Passive sampler; Environmental exposure; Resident; Farmer
Attached files
Description Individuals are exposed to pesticides via dietary and non-dietary exposure routes. There is a growing need for aggregated exposure estimates across occupationally and non-occupationally exposed populations. Exposure to current-use and legacy pesticides was studied using silicone wristbands worn by farmers, residents living close to treated fields (neighbors), and the general population (consumers), in total, 641 participants across 10 European countries. Wristband extracts were analyzed for 193 pesticides by targeted Liquid and Gas Chromatography-Mass Spectrometry. Information on exposure predictors, such as frequency of cleaning, was collected by questionnaire. Logistic regressions and multivariable generalized least squares models were used to study predictors of pesticide occurrence and concentrations, respectively. We detected 173 out of 193 pesticides (89 %) across all samples. Per wristband 9 - 74 (median of 36) pesticides were detected in conventional farmers (FC), 8 - 66 (median of 20) in organic farmers, 3 - 66 (median of 20) in neighbors and 2 - 54 (median of 17) in consumers. Insecticides, like permethrin and chlorpyrifos, were commonly detected across all groups (>85 %). Concentrations varied significantly across groups, with the highest levels often observed in FC. We identified pesticide use and having pets as important predictors of personal non-dietary exposure. Mixture analysis revealed one major combination (in 72 % of all samples) of three insecticides, namely permethrin, chlorpyrifos, DDE p,p', and the synergist piperonyl butoxide. This study highlights that farm workers using a conventional farming system are a highly exposed group. It is unclear what the identified prevalent mixtures mean for cumulative exposure and resulting health risks.
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