A review of plasma modification strategies of nanomaterials for wastewater treatment

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Authors

FATIMA Areej ZAŽÍMAL František HOMOLA Tomáš

Year of publication 2025
Type Article in Periodical
Magazine / Source Journal of Water Process Engineering
MU Faculty or unit

Faculty of Science

Citation
web https://doi.org/10.1016/j.jwpe.2025.108350
Doi https://doi.org/10.1016/j.jwpe.2025.108350
Keywords Nanomaterials (NMs); Cold plasma; Photocatalysis; Wastewater treatment; Plasma modifications
Description The discharge of wastewater into aquatic environments has emerged as a major environmental concern in recent decades. The capture and degradation of pollutants in wastewater using nanomaterials (NMs) has emerged as a cost-effective and highly efficient strategy through adsorption, membrane filtration, and advanced oxidation processes (AOPs), including heterogeneous photocatalysis. This review examines NMs features that influence their optoelectronic properties and resulting performance in the AOPs that can be employed in wastewater treatment. This work particularly highlights the modification of NMs by low-temperature and atmospheric pressure plasmas e.g., dielectric barrier discharge, plasma jet, corona and gliding arc discharge. These plasma modification strategies are favored over conventional chemical methods due to their minimal waste generation, production of non-toxic byproducts, preservation of bulk material properties, solvent-free (dry) operation, rapid, energy-efficient processing, and scalability to large areas. Emphasis is placed on defect engineering, the generation of oxygen vacancies, and surface functionalization of NMs by plasma. These key factors can shift the band gap of NMs, improve charge carrier separation, boost reactive oxygen species formation, provide additional pathways for charge transfer, enhance visible light response, and increase surface area. Collectively, these effects alter the performance of NMs in pollutant degradation.
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